Physique aux interfaces : Matière molle, Biologie, Santé

Interface biologie santé

Plasmonique

Physique interfaces biologiques

Several projects of our team are devoted to the study of soft matter physical properties as their mechanical, thermal or structural properties under different environments.

Researchers

Guillaume Brotons
Philippe Daniel
Nicolas Delorme
Mathieu Edely
Nicolas Errien
Alain Gibaud
Fabienne Lagarde
Olivier Noël

Nano-mechanics of soft matter

Related papers

Et-Thakafy, O., Delorme, F. Guyomarc’h, and C. Lopez, Mechanical properties of milk sphingomyelin bilayer membranes in the gel phase: Effects of naturally complex heterogeneity, saturation and acyl chain length investigated on liposomes using AFM. Chemistry and Physics of Lipids, 2018. 210: p. 47-59, DOI: https://doi.org/10.1016/j.chemphyslip.2017.11.014.
Et-Thakafy, O., Delorme, C. Gaillard, C. Mériadec, F. Artzner, C. Lopez, and F. Guyomarc’h, Mechanical Properties of Membranes Composed of Gel-Phase or Fluid-Phase Phospholipids Probed on Liposomes by Atomic Force Spectroscopy. Langmuir, 2017. 33(21): p. 5117-5126, DOI: 10.1021/acs.langmuir.7b00363.
Ayche, K., A. Ventura, F. Bardeau, B. Minisini, J.F. Pilard, and N. Delorme, Natural rubber based thin coating for MEMS encapsulation. Progress in Organic Coatings, 2016. 99: p. 308-313, DOI: http://dx.doi.org/10.1016/j.porgcoat.2016.06.010.

Projects

Mecacell

Structural properties of polymers and complex composites films

Several techniques mastered in the team allow deep polymer characterization providing structural and physical information.

Since both infrared and Raman spectroscopies give complementary information, we use these techniques as effective tools to monitor the molecular structure and properties of polymers. Coupled with chemometrics, vibrational spectroscopies are used in the team to control polymer structure under different environments (thermal degradation, UV ageing, mechanical deformation, very thin films behaviors); to develop new bio-based polymers (cellulose, natural rubber) and to assess the distribution of fillers in composite polymers.

We have also developed a strong expertise in X-ray reflectivity....

Related papers

Anisotropic One-Dimensional Aqueous Polymer Gel Electrolyte for Photoelectrochemical Devices: Improvement in Hydrophobic TiO₂–Dye/Electrolyte InterfaceKK Sonigara, JV Vaghasiya, HK Machhi, J Prasad, A Gibaud, SS Soni. ACS Applied Energy Materials, 2018
New proton conducting membrane based on bacterial cellulose/polyaniline nanocomposite film impregnated with guanidinium-based ionic liquid, S. Rogalsky, -F. Bardeau, S. Makhno, N. Babkina, O. Tarasyuk, T. Cherniavska, I. Orlovska, N. Kozyrovska, O. Brovko, Polymer 142, 183-195 (2018)
K. Taksapattanakul, T. Tulyapitak, P. Phinyocheep, P. Ruamcharoen, J. Ruamcharoen , F. Lagarde, M. Edely, P. Daniel. Raman investigation of thermoplastic vulcanizates based on hydrogenated natural rubber/polypropylene blends. Polymer Testing. 57 107-114 (2017)
Ghamrawi, J.-P. Bouchara, O. Tarasyuk, S. Rogalsky, L. Lyoshina, O. Bulko, J.-F. Bardeau, Promising silicones modified with cationic biocides for the development of antimicrobial medical devices, Materials Science and Engineering C 75, 969–979 (2017)
Taksapattanakul, T.Tulyapitak, P. Phinyocheep, P. Ruamcharoen, J. Ruamcharoen, Lagarde, P. Daniel The Effect of Percent Hydrogenation and Vulcanization System on Ozone Stability of Hydrogenated Natural Rubber Vulcanizates using Raman Spectroscopy. Polymer Degradation and Stability, 141 58-68 (2017)
JV Vaghasiya, KK Sonigara, T Beuvier, A Gibaud, SS Soni, Iodine induced 1-D lamellar self assembly in organic ionic crystals for solid state dye sensitized solar cells, Nanoscale 9 (41), 15949-15957, 2017
Chebil, M.S., G. Vignaud, J.K. Bal, T. Beuvier, Delorme, Y. Grohens, and A. Gibaud, Reversibility in glass transition behavior after erasing stress induced by spin coating process. Polymer, 2017. 122: p. 45-51, DOI: https://doi.org/10.1016/j.polymer.2017.06.044.
JV Vaghasiya, KK Sonigara, J Prasad, T Beuvier, A Gibaud, SS Soni, Role of a phenothiazine/phenoxazine donor in solid ionic conductors for efficient solid state dye sensitized solar cells, Journal of Materials Chemistry A 5 (11), 5373-5382, 2017
Unni, A.B., G. Vignaud, J.P. Chapel, J. Giermanska, J.K. Bal, Delorme, T. Beuvier, S. Thomas, Y. Grohens, and A. Gibaud, Probing the Density Variation of Confined Polymer Thin Films via Simple Model-Independent Nanoparticle Adsorption. Macromolecules, 2017. 50(3): p. 1027-1036, DOI: 10.1021/acs.macromol.6b02617.
Beena Unni, A., G. Vignaud, J.K. Bal, Delorme, T. Beuvier, S. Thomas, Y. Grohens, and A. Gibaud, Solvent Assisted Rinsing: Stability/Instability of Ultrathin Polymer Residual Layer. Macromolecules, 2016. 49(5): p. 1807-1815, DOI: 10.1021/acs.macromol.5b02435.
Ayche, A. Ventura, J.-F. Bardeau, B. Minisini, J.-F. Pilard, N. Delorme, Natural rubber based thin coating for MEMS encapsulation, Progress in Organic Coating 99, 308-3013 (2016)
Rogalsky, J.-F. Bardeau, H. Wu, L. Lyoshina, O. Bulko, O. Tarasyuk, S. Makhno, T. Cherniavska, Y. Kyselov, J. H. Koo, Structural, thermal and antibacterial properties of polyamide 11/polymeric biocide polyhexamethylene guanidine dodecylbenzenesulfonate composites, Journal of Materials Science 51, 7716-7730 (2016)
Hodyna, J.-F. Bardeau, L. Metelytsia, S. Riabov, L. Kobrina, S. Laptiy, L. Kalashnikova, V. Parkhomenko, O. Tarasyuk, S. Rogalsky, Efficient antimicrobial activity and reduced toxicity of 1-dodecy1-3-methylimidazolium tetrafluoroborate ionic liquid/beta-cyclodextrin complex, Chemical Engineering Journal 284, 1136-1145 (2016)
A . Gibaud, J.K. Bal, E.M. Gullikson, C. Wang and G. Vignaud, AIP Advances, 6 (9), 095016, 2016
K. Bal, T. Beuvier, A.B. Unni,E. Chavez, G. Vignaud, N. Delorme, M. Chebil,. Grohens, A. Gibaud, ACS Nano, 9, 8184, 2015
Delorme, N., M.S. Chebil, G. Vignaud, V. Le Houerou, F. Bardeau, R. Busselez, A. Gibaud, and Y. Grohens, Experimental evidence of ultrathin polymer film stratification by AFM force spectroscopy. Eur. Phys. J. E, 2015. 38: p. 56.
Bal, J.K., T. Beuvier, A.B. Unni, E.A. Chavez Panduro, G. Vignaud, Delorme, M.S. Chebil, Y. Grohens, and A. Gibaud, Stability of Polymer Ultrathin Films (<7 nm) Made by a Top-Down Approach. ACS Nano, 2015. 9(8): p. 8184-8193, DOI: 10.1021/acsnano.5b02381.

Publié le 9 juillet 2024

Interface polymère

Impact des interfaces sur les propriétés des polymères

Interaction avec l'environnement

The metallic nanoparticles or nanostructures can strongly interact with light. They can provide some huge enhancement of the near field at the vicinity of the metallic surface due to the excitation of the localised surface plasmon (LSP). The plasmonic properties depend on geometrical parameters (size, shape, coupling...) of the nanopatterned metals and can be finely controlled and tuned on a wide range of wavelength.

Researchers

Alain Bulou
Philippe Daniel
Nicolas Delorme
Mathieu Edely
Nicolas Errien
Alain Gibaud
Fabienne Lagarde
Marc Lamy de La Chapelle

Field enhancement and SERS optimization

We work on the relation between the LSP and the enhancement efficiency depending on the geometrical parameters of the dedicated nanostructures. We notably determine the influence of the LSP on the surface enhanced Raman scattering (SERS).

Moreover, in the team, we developed strong skills in the structuration of metallic surfaces at micro/nanoscales to create nanostructured substrates for highly sensitive SERS applications.

Related papers

Mathieu Edely, Nicolas Delorme, David Siniscalco, and Jean-François Bardeau, Mater. Technol. 2018, 1800134 - DOI: 10.1002/admt.201800134
Quilis, M. Lequeux, P. Venugopalan, I. Khan, W. Knoll, S. Boujday, M. Lamy de la Chapelle, J. Dostalek, Tunable laser interference lithography preparation of plasmonic nanoparticle arrays tailored for SERS, Nanoscale, 10, 10268, 2018
Gillibert, F. Colas, R. Yasukuni, G. Picardi, M. Lamy de la Chapelle, Plasmonic Properties of Aluminium Nanocylinders in the Visible Range, J. Phys. Chem. C 121(4), 2402, 2017
Gillibert, T. Tafer, M. Lamy de la Chapelle, Strong coupling between localized surface plasmon and Bragg mode on aluminium nanocylinders grating deposited on aluminium film, Physica Status Solidi a, 214(8), 1600793, 2017
Colas, M. Cottat, R. Gillibert, N. Guillot, N. Djaker, N. Lidgi-Guigui, T. Toury, D. Barchiesi, A. Toma, E. Di Fabrizio, P. G. Gucciardi, M. Lamy de la Chapelle, Red-Shift Effects in Surface Enhanced Raman Spectroscopy: Spectral or Intensity Dependence of the Near-Field?, J. Phys. Chem. C120 (25), 13675, 2016
Gillibert, M. Sarkar, J. F. Bryche, R. Yasukuni, J. Moreau, M. Besbes, G. Barbillon, P. Gogol, B, Bartenlian, M. Canva, M. Lamy de la Chapelle, Directional Surface Enhanced Raman Scattering on gold nano-gratings, Nanotechnology 27/11, 115202, 2016
Gillibert, M. Sarkar, J. Moreau, M. Besbes, M. Canva, M. Lamy de la Chapelle, Near Field Enhancement Localization on Plasmonic Gratings, J. Phys. Chem. C 120 (48), 27562, 2016
F. Bryche, R. Gillibert, G. Barbillon, P. Gogol, J. Moreau, M. Lamy de la Chapelle, B. Bartenlian, M. Canva, Plasmonic enhancement by a continuous gold underlayer: application to SERS sensing, Plasmonics, 11/2, 601, 2016
F. Bryche, A. Tsigara, B. Bélier, M. Lamy de la Chapelle, M. Canva, B. Bartenlian, G. Barbillon, Surface enhanced Raman scattering improvement of gold triangular nanoprisms by a gold reflective underlayer for chemical sensing, Sensor and actuator B, 228, 31, 2016

Patent: Procédé de Fabrication d’un motif métallique nanostructuré et motif métallique- Inventeurs : M. Edely, N. Delorme, J.-F. Bardeau (2014 - N° de dépôt : 1461880)

Projects

Molecular plasmonics and thermoplasmonics

The plasmonic properties of metallic nanostructures can induced side effects such as local increase of the temperature, known as thermoplasmonics effect, or the formation of hot electrons that can react with molecules. We study and exploit such properties. For instance, we demonstrated that some chemical reaction, such as the click chemistry, can be initiated and mediated by the plasmon or that large temperatures can be reached at the nanostructure surface to heat the local medium.

Related papers

Tijunelyte, E. Guenin, N. Lidgi-Guigui, F. Colas, J. Ibrahim, T. Toury, Lamy de la Chapelle, Nanoplasmonics tuned “click chemistry”, Nanoscale, 7/13, 7105, 2016
Betelu, I. Tijunelyte, L. Boubekeur-Lecaque, I. Ignatiadis, J. Ibrahim, S. Gaboreau, C. Berho, T. Toury, E. Guenin, N. Lidgi-Guigui, N. Félidj, E. Rinnert, Marc Lamy de la Chapelle, Evidence of the Grafting Mechanisms of Diazonium Salts on Gold Nanostructures, J. Phys. Chem. C, 120 (32), 18158, 2016
Picardi, F. Colas, R. Gillibert, M. Lamy de la Chapelle, Spectral Shift of the Plasmon Resonance between the Optical Extinction and Absorption of Gold and Aluminum Nanodisks, J. Phys. Chem. C, 120 (45), 26025, 2016
Tijunelyte, I. Kherbouche, S. Gam-Derouich, M. Nguyen, N. Lidgi-Guigui, Lamy de la Chapelle, A. Lamouri, G. Levi, J. Aubard, A. Chevillot-Biraud, C. Mangeney, N. Felidj, Multi-functionalization of lithographically designed gold nanodisks by plasmon-mediated reduction of aryl diazonium salts, Nanoscale Horizon, 3, 53, 2018

Projects

X-TREM

Plasmonic applications in sensing

The field enhancement can be exploited for large enhancement of the spectroscopical signal of any molecules located at the vicinity of the nanoparticle surface. It is then possible to detect molecular species at low concentration and provide high sensitivity to the detection. Thus, several projects were devoted to the enhancement of Raman signal (SERS) allowing the detection and analysis of molecules in very small concentrations. Most applications are turned towards the detection of biomolecules in medecine, pollutants in environment, contaminants and micro-organisms in food.

Related papers

Gillibert, M. Triba, Marc Lamy de la Chapelle, Surface Enhanced Raman Scattering Sensor for Highly Sensitive and Selective Detection of Ochratoxin A, Analyst, 143, 339, 2018.
Gillibert, J. Q. Huang, Y. Zhang, W. L. Fu, M. Lamy de la Chapelle Explosive detection by Surface Enhanced Raman Scattering, Trend in Analytical Chemistry, 105, 166, 2018
Gillibert, J. Q. Huang, Y. Zhang, W. L. Fu, M. Lamy de la Chapelle Food quality control by Surface Enhanced Raman Scattering, Trend in Analytical Chemistry, 105, 185, 2018
Cottat, R. Yasukuni, Y. Homma, N. Lidgi-Guigui, N. Varin-Blank, M. Lamy de la Chapelle, C. Le Roy, Phosphorylation impact on Spleen Tyrosine kinase conformation by Surface Enhanced Raman Spectroscopy, Scientific Reports 7, 39766, 2017.
Chauvet, R., Lagarde, T. Charrier, A. Assaf, G. Thouand, and P. Daniel. “Microbiological Identification by Surface-Enhanced Raman Spectroscopy.” Applied Spectroscopy Reviews 52, no. 2 (2017). https://doi.org/10.1080/05704928.2016.1209760
Tijunelyte, S. Betelu, J. Moreau, I. Ignatiadis, C. Berho, N. Lidgi-Guigui, E. Guenin, C. David, S. Vergnole, E. Rinnert, Marc Lamy de la Chapelle, Diazonium Salt-Based Surface-Enhanced Raman Spectroscopy Nanosensor: Detection and Quantitation of Aromatic Hydrocarbons in Water Sample, Sensors, 17(6), 1198, 2017
Dribek, E. Rinnert, F. Colas, M.-P. Crassous, N. Thioune, C. David, M. Lamy de la Chapelle, C. Compère, Organometallic nanoprobe to enhance optical response on the polycyclic aromatic hydrocarbon benzo[a]pyrene immunoassay using SERS technology, Environmental Science and Pollution Research, 24(35), 27070, 2017
Alami, A. El, Lagarde, U. Tamer, M. Baitoul, and P. Daniel. “Enhanced Raman Spectroscopy Coupled to Chemometrics for Identification and Quantification of Acetylcholinesterase Inhibitors.” Vibrational Spectroscopy 87 (2016). https://doi.org/10.1016/j.vibspec.2016.09.005.
Enhanced Vibrational Spectroscopies as Tools for Small Molecule Biosensing, Boujday, M. Lamy de la Chapelle, J. Srajer, W. Knoll, Sensors, 15, 21239, 2015
Cottat, C. D’Andrea, R.Yasukuni, N. Malashikhina, R. Grinyte, N. Lidgi-Guigui, B. Fazio, A. Sutton, O. Oudar, N. Charnaux, V. Pavlov, A. Toma, E. Di Fabrizio, P. G. Gucciardi M. Lamy de la Chapelle , High Sensitivity, High Selectivity SERS Detection of MnSOD Using Optical Nanoantennas Functionalized with Aptamers, J. Phys. Chem. C 119 15532, 2015.