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Recycling and bio-sourced building blocks

Recycling and bio-sourced building blocks

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Useful building blocks from natural rubber

A portfolio of oligomers obtained from natural rubber or waste tyres has been obtained so far in the team. Molecular mass is easily tuned and chain end functionalization allows the generation of different building blocks that have been used in the synthesis of new biobased materials, such as polyurethane films and foams, non-isocyanate polyurethane, cross-linked thin and thick films. A number of properties can be inferred to these materials varying the formulation, such as being flame retardant, antibacterial, antifouling, biodegradable, so they can be used in a great number of applications.

 

Researchers

  • Pamela Pasetto
  • Jean-François Pilard

Related papers

  • JF Pilard, A. Nourry, K.V.B. Nesan, US Patent 2018,  15/745,628.
  • Jaratrotkamjorn, R., Nourry, A., Pasetto, P., Choppé, E., Panwiriyarat, W., Tanrattanakul, V.Pilard, J.-F. (2017), Appl. Polym. Sci., 134, 45427.
  • Mouawia, A. Nourry, A.-C. Gaumont, J.-F. Pilard, I. Dez , ACS Sustainable Chem. Eng. 2017, 5, 696−700
  • Rattanapan, P.Pasetto, J.-F. Pilard, V. Tanrattanakul, J. App. Pol. Sci., 2016, 133, 44251 (1-10).
  • Rattanapan, P. Pasetto,  J.-F. Pilard,V. Tanrattanakul, J Polym Res, 2016, 23, 182.
  • K. N. Tran, G. Colomines, E. Leroy, A. Nourry, J-F Pilard, R. Deterre, 2016, 133, 43548.
  • Badawy H., Brunellière J., Veryaskina M., Brotons G., Sablé S., Lanneluc I., Lambert K., Marmey P., Milsted A., Cutright T., Nourry A.,Mouget J.-L., Pasetto P., J. Mol. Sci. 2015, 16(3), 4392-4415.
  • K. N.Tran, J.-F. Pilard, P. Pasetto, Journal of Applied Polymer Science, 2015, 132(1) 41326.
  • Chumeka, P. Pasetto, J.-F. Pilard, V. Tanrattanakul, Journal of Applied Polymer Science, 2015, 132 (6).
  • Chumeka, P. Pasetto, J.-F. Pilard, V. Tanrattanakul, Polymer, 2014, 55, 478- 4487.
  • Mouawia, A. Nourry, A.-C. Gaumont, J.-F. Pilard, I. Dez , Actualité Chimique, 2014, 390, 88-89.
  • Kaogong, J. Suwanmanee, J-F Pilard, P.Pasetto, V. Tanrattanakul, Kei Engineering Materials, 2013, 531-532 (Material Science and nanotechnology I), 317-320
  • T. Badawy, P.Pasetto, J-L Mouget, J-F.Pilard, T. J. Cutright, A. Milsted, Biochem. Biophys. Res.Commun., 2013, 438, (4), 691–696.
  • Jellali, I. Campistron, P. Pasetto, A. Laguerre, F. Gohier, C. Hellio, JF Pilard, JL Mouget, Progress in Organic Coatings, 2013, 76(9),1203-1214.
  • Panwiriyarat, V. Tanrattanakul, J-F Pilard, P. Pasetto, C.Khaokong, Advanced Science letters, 2013, 19(3), 1016-1020.
  • Panwiriyarat, V. Tanrattanakul, JF Pilard, P.Pasetto, C. Khaokong, Journal of Applied Polymer Science, 2013, 130 (1), 453-462.
  • Panwiriyarat, V. Tanrattanakul, J-F Pilard, P. Pasetto, C.Khaokong, Journal of Polymers and the Environment, 2013, 21, (3), 807-815.
  • Chumeka, V. Tanrattanakul, J.F. Pilard, P. Pasetto, Journal of Polymers and the Environment, 2013, 21 (2), 450-460.
  • Jellali, I. Campistron, A. Laguerre, L. Lecamp, P. Pasetto, C. Bunel, J.L. Mouget, J.-F. Pilard, Journal of Applied Polymer Science, 2013, 128, 4, 2489–2497.
  • Jellali, R.; Campistron, I.; Laguerre, A.; Pasetto, P.; Lecamp, L.; Bunel, C.; Mouget, J.-L.; Pilard, J.-F., Journal of Applied Polymer Science, 2013,127, 2, 1359–1368.
  • Sadaka, I. Campistron, A. Laguerre, J-F Pilard, Polymer Degradation and Stability, 2013, 98(3), 736-742.

Green recycling of unsatured elastomersFrom waste tyres to smart polyurethanes

Smart polyurethanes were developed from various well defined heterofunctional oligomers obtained through a highly controlled oxidative or methatetic cleavage of unsaturated high molecular weight rubbers. These two methodologies  applicable from either natural source or waste rubber materials allow the access to new materials (antibacterial coatings, flame retardant foams, ionogels,etc…)

 

Researchers

  • Pamela Pasetto
  • Jean-François Pilard

Related papers

  • JF Pilard, A. Nourry, K.V.B. Nesan, US Patent 2018,  15/745,628.
  • Mouawia, A. Nourry, A.-C. Gaumont, J.-F. Pilard, I. Dez, “Controlled Metathetic Depolymerization of Natural Rubber in Ionic Liquids: From Waste Tires to Telechelic Polyisoprene Oligomers”, ACS Sustainable Chem. Eng. 2017, 5, 696−700.
  • Rattanapan, P.Pasetto, J.-F. Pilard, V. Tanrattanakul, “Polyurethane foams from oligomers derived from waste tire crumbs and polycaprolactone diols”, Journal of Applied Polymer Science, 2016, 133, 44251 (1-10).
  • K. N. Tran, G. Colomines, E. Leroy, A. Nourry, J-F Pilard, R. Deterre, “Rubber-based acrylate resins: an alternative for tire recycling and carbon neutral thermoset materials design”, J Journal of Applied Polymer Science, 2016, 133, 43548.
  • K. N.Tran, J.-F. Pilard, P. Pasetto, “Recycling Waste Tires: Generation of Functional Oligomers and Description of Their Use in the Synthesis of Polyurethane Foams”, Journal of Applied Polymer Science, 2015, 132(1) 41326.
  • Mouawia, A. Nourry, A.-C. Gaumont, J.-F. Pilard, I. Dez “Valorisation des déchets élastomères: du déchet pneumatique au polymère fonctionnel ”, Actualité Chimique, 2014, 390, 88-89.
  • Sadaka, I. Campistron, A. Laguerre, J-F Pilard, “Telechelic oligomers obtained by metathetic degradation of both polyisoprene and styrene–butadiene rubbers. Applications for recycling waste tyre rubber”, Polymer Degradation and Stability, 2013, 98(3), 736-742.
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